Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 30, Pages 10382-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja903513e
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Funding
- European Union
- Royal Society for a Wolfson Research Merit Award
- NSERC of Canada
- EPSRC
- Engineering and Physical Sciences Research Council [EP/F056974/1] Funding Source: researchfish
- EPSRC [EP/F056974/1] Funding Source: UKRI
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Water-soluble, high-molecular-weight polycobaltocenium polyelectrolytes have been prepared by ring-opening polymerization (ROP) techniques. Anionic polymerization of a strained 19-electron dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium chloride resulted in the formation of oligomers with up to nine repeat units. Thermal ROP of dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium nitrate resulted in the formation of high-molecular-weight polycobaltocenium nitrate, a redox-active cobalt-containing polyelectrolyte.
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