Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 13, Pages 4590-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9005223
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- Research Corporation
- Office of Basic Energy Sciences (BES), Division of Materials Sciences, U.S. Department of Energy (DOE) [DE-FG02-86ER45259, DE-AC02-8CH10886]
- EPSRC, UK
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X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz)(2)(S2O8) consists of 2D square nets of Ag2+ ions resulting from the corner-sharing of axially elongated AgN4O2 octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, mu+SR measurements indicate that Ag(pyz)(2)(S2O8) undergoes 3D magnetic ordering below 7.8(3) K.
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