Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 47, Pages 17076-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja907156j
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Funding
- JSPS
- Mitsubishi Chemical Corporation Fund
- Sumitomo Foundation
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In the diastereodifferentiating Paterno-Buchi reaction, the excited CT complex was distinctly different in structure and reactivity from the conventional exciplex, and the inherent diastereofacial selectivity and its temperature dependence were opposite to each other in these two excitation modes. Thus, the combined use of wavelength and temperature not only reveals the mechanistic details but also provides a new. convenient, powerful tool. for critically controlling the stereochemical outcomes of asymmetric photoreactions.
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