Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 15, Pages 5368-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8097096
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Funding
- Austrian Science Fund [P18381]
- European Commission [MRTN-C7-2006-035866]
- Austrian Science Fund (FWF) [P18381] Funding Source: Austrian Science Fund (FWF)
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An enzyme preparation of Trametes hirsuta cleaves alkenes following neither the classical dioxygenase mechanism nor via a monooxygenase mechanism. A catalytic cycle for an alternative enzymatic alkene cleavage was proposed, whereby two oxygen atoms derived from two different oxygen molecules are incorporated into the product(s).
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