Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 46, Pages 16646-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9077842
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Funding
- 973 Program [2006CB300402, 2007CB815307]
- NSFC [20821003, 20673088, 20425312, 20721001, 20423002]
- Xiamen University (Mingjiang Professorship)
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For the first time, we have produced the stable compound Sc4C2@C-80-I-h and characterized it as a metal carbide endofullerene by FTIR and Raman spectroscopies in combination with DFT calculations. Furthermore, DFT calculations have demonstrated that this molecule has a Russian-doll-type structure, C-2@Sc-4@C-80.
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