4.8 Article

Ir-Catalyzed Cross-Coupling of Styrene Derivatives with Allylic Carbonates: Free Amine Assisted Vinyl C-H Bond Activation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 24, Pages 8346-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja901384j

Keywords

-

Funding

  1. NSFC [20872159, 20821002]
  2. National Basic Research Program of China (973 Program) [2009CB825300]
  3. STCSM [07pj14106, 07JC14063]

Ask authors/readers for more resources

Iridium complex derived from [Ir(COD)Cl](2)/Feringa's Ligand is an efficient catalytic system for the cross-coupling reaction between allyl. carbonates and o-amino styrene derivatives, affording skipped Z, E dienes. The reaction features ready availability of the starting materials, mild reaction conditions, high yields, and excellent stereoselectivity.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available