Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 42, Pages 15116-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9071805
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- National Science Council
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The first mixed-valence uranium(IV,V) silicate is synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains chains of corner-sharing (UO6)-O-IV,V octahedra which are interconnected by Si4O12 four-membered rings to form a 3-D framework. XPS and XANES spectra were measured to identify the valence state of uranium.
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