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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 22, Pages 6916-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja801232t
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A system with coupled catalytic cycles is described that allows radical reduction by hydrogen atom abstraction from rhodium hydrides. These intermediates are generated from H-2 activation by Wilkinson's catalyst. Radical generation is carried out by titanocene-catalyzed electron transfer to epoxides.
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