4.8 Article

Intra/intermolecular direct allylic alkylation via Pd(II)-catalyzed allylic C-H activation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 39, Pages 12901-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja803452p

Keywords

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Funding

  1. Peking University
  2. National Sciences of Foundation of China [20542001, 20521202]
  3. 973 program [2009CB825300]
  4. Chun-Tsung Scholars

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The first catalytic direct alkylation of allylic C-H bonds via Pd(II)-catalysis is described in the absence of base. Polysubstituted cyclic compounds can also be constructed by the intramolecular direct allylic alkylation.

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