Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 35, Pages 11650-11661Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja803783c
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Funding
- U.S. Departrnent of Energy [DE-FG36-05GO15001, DE-FG02-08ER15935]
- BASF (Ludwigshafen, Germany)
- Korea Research Foundation [KRF 2003-070-CO0029]
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Metal-organic polyhedra and frameworks (MOPS and MOFs) were prepared by linking square units M-2(CO2)(4) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPS and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115, -116, -117, -118, -119, -222, -601, -602, -603, -604) and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures.
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