Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 43, Pages 14082-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8063827
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Funding
- The Scripps Research Institute
- U.S. National Science Foundation (NSF) [CHE-0615716]
- Camille and Henry Dreyfus Foundation
- A. P. Sloan Foundation
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A Pd(II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The reaction conditions are also applicable for the carboxylation of vinyl C-H bonds, The first C-H insertion Pd-aryl complex from carboxylic acids has been characterized by X-ray crystallography.
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