Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 23, Pages 7244-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja802494z
Keywords
-
Categories
Ask authors/readers for more resources
The structure and chemical bonding of B-16(-) were studied using ab initio calculations and photoelectron spectroscopy. Its global minimum is found to be a quasi-planar and elongated structure (C-2h). Addition of an electron to B-16(-) resulted in a perfectly planar and closed shell B-16(2-) (D-2h), which is shown to possess 10 pi electrons with a pi-bonding pattern similar to that of naphthalene and can thus be considered as an all-boron naphthalene, a new member in the growing family of hydrocarbon analogues of boron clusters.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available