4.8 Article

CO2 coordination by inorganic polyoxoanion in water

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 33, Pages 10838-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja801560t

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Funding

  1. National Natural Science Foundation of China [20671017, 20731002]
  2. Specialized Research Fund

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Two inorganic polyoxoanions react with carbon dioxide in aqueous solution to yield two polymeric chainlike complexes, where an activated CO2 molecule covalently bonds to polyoxoanions in a linear mu-eta(1),eta(1)-OCO style. For the first time, the CO2 coordination is realized by an economic and environmentally friendly approach.

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