Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 9, Pages 2722-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja710238h
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- NIGMS NIH HHS [GM026782] Funding Source: Medline
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A convergent and highly stereocontrolled synthesis of (+)-superstolide A (1) has been accomplished. Key steps of this synthesis include the intramolecular Suzuki reaction of 26 and the highly diastereoselective transannular Diels-Alder cyclization of macrocyclic octaene 3.
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