Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 42, Pages 13834-13835Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja804944r
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Funding
- NSF [CHE-0809776]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0809776] Funding Source: National Science Foundation
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A family of highly porous homochiral, racemic, and meso metal-organic frameworks (MOFs) were synthesized based on a new elongated tetra-carboxylate ligand and the copper paddle-wheel building units. These MOFs exhibited remarkable catenation isomerism that is controlled by both chirality of the bridging ligand and the size of solvent molecules. The ability to manipulate framework interpenetration is key to future synthesis os mesoporous homochiral MOFs which hold great promise in heterogeneous asymmetric catalysis and chiral separations.
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