Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 38, Pages 12558-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja803018w
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- Deutsche Forschungsgemeinschaft (DFG)
- SFB 486
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The applicability of click chemistry for high-density functionalization of mesoporous silica is demonstrated. The mild conditions of the copper(I)-catalyzed Huisgen reaction allow for a surface functionalization with intact biomolecules. The high covalent enzyme functionalization density under simultaneous retention of enzyme activity and the absence of leaching demonstrate the promising potential of this approach.
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