Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 8, Pages 2394-2395Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja078308e
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Funding
- National Research Foundation of Korea [2005-070-C00078] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A rational approach to fluorescence turn-on sensing of amino carboxylates is described, which primarily relies on the perturbation of the quenching n-pi* transiton energy level of a carbonyl ionophore relative to the pi-pi* transition energy level of an anthracene in the sensor. The anthracene-based bis (trifluoroacetylcarboxanilide) sensor is structurally simple but selectively senses alpha-amino acids as their carboxylate forms over beta and gamma-homologues, by forming a (1:1)-cyclic adduct with a large fluorescence enhancement factor of 110.
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