4.8 Article

Helical carbon and graphitic films prepared from iodine-doped helical polyacetylene film using morphology-retaining carbonization

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 33, Pages 10880-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja803865e

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
  2. Nanotechnology Support Project of the MEXT
  3. Grants-in-Aid for Scientific Research [20225007] Funding Source: KAKEN

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In this communication, we report a novel preparation of the helical carbon nanofibril-fabricated thin film from the iodine-doped filmy helical polyacetylene through a carbonization process. Carbonization of the helical polyacetylene films by way of iodine doping is found to afford carbon and graphitic films completely preserving morphologies and even helical nanofibril structures.

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