Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 49, Pages 16472-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8065539
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Funding
- National Science Foundation [CHE-0616577]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0911092] Funding Source: National Science Foundation
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Contamination of active pharmaceutical ingredients and healthcare products with oxidized forms of palladium and platinum are important problems. We report a convenient fluorogenic probe based on the catalyzed aromatic Claisen rearrangement capable of detecting Pd-II and Pt-IV. Using this probe, we can fluorescentty detect Pd-III in functionalized organic compounds and Pt-IV in Pt-0-water without sample pretreatment. This method may find broad applications in the pharmaceutical industry, the environment, and Pd/Pt quality control.
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