4.8 Article

Self-assembly of a 3-D triply interlocked chiral [2]catenane

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 10, Pages 2950-2951

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja8002149

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Funding

  1. Engineering and Physical Sciences Research Council [EP/E023517/1, EP/C010973/1] Funding Source: researchfish
  2. EPSRC [EP/E023517/1] Funding Source: UKRI

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A tripodal cyclotriveratrylene-based ligand with chelating 2,2'-bipyridine arms self-assembles with either Zn(NO3)(2) or Co(NO3)(2) to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.

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