Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 42, Pages 13856-13857Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8061002
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Funding
- Grants-in-Aid for Scientific Research [17GS0207, 20036024]
- Ministry of Education, Culture, Sports, Science and Technology of Japan
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Synthesis and isolation of the stable diaryldibromodisilene, Bbt (Br)Si =(Br)Bbt, has been accomplished for the first time. The dibromodisilene underewent substitution reactions with organometallic reagents on the low-coordinated silicon atom to afford the corresponding substituted disilenes. Futhermore, the reaction of 1 with t-BuLi afforded the corresponding 1,2-diaryldisilyne, BbtSi SiBbt, the characters of which were revealed by spectroscopic and crystallographic analyses.
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