Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 45, Pages 14970-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja807828t
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Funding
- National Science Foundation [CHE-0608142, CHE-0716718, CHE-0749868]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [749868] Funding Source: National Science Foundation
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The potassium graphite reduction of L:PCl(3) leads to the formation of carbene-stabilized diphosphorus molecules, L:P-P:L, 1 (L: = :C{N (2,6-Pr(2)(i)C(6)H(3))CH}(2)) and 2 (L: = :C{N(2,4,6-Me(3)C(6)H(2))CH}2), respectively. The nature of the bonding in 1 and 2 was delineated by DFT computations.
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