Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 30, Pages 9642-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8026168
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Funding
- BBSRC [BB/E004350/1] Funding Source: UKRI
- EPSRC [EP/E000614/1] Funding Source: UKRI
- Biotechnology and Biological Sciences Research Council [EGA17763, BB/E004350/1] Funding Source: Medline
- Biotechnology and Biological Sciences Research Council [BB/C510824/1, BB/E004350/1, EGA17763] Funding Source: researchfish
- Engineering and Physical Sciences Research Council [GR/T26542/01, EP/D023335/1, EP/E000614/1, EP/D023343/1] Funding Source: researchfish
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Allyl sulfides undergo efficient cross-metathesis in aqueous media with Hoveyda-Grubbs second generation catalyst 1. The high reactivity of allyl sulfides in cross-metathesis was exploited in the first examples of cross-metathesis on a protein surface. S-Allylcysteine was incorporated chemically into the protein, providing the requisite allyl sulfide handle. Preliminary efforts to genetically incorporate S-allylcysteine into proteins are also reported.
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