Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 48, Pages 16140-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja806113v
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Funding
- NIGMS [GM-59417]
- Merck
- NSF [DBI-0619576]
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The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio- and stereoselective fashion employing a stoichiometric amount of bis(pinacolato)diboron. This reductive Coupling furnishes an allyl boronic ester as the reaction product, a Compound which was readily converted to the derived allylic alcohol by oxidative workup.
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