Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 4, Pages 1146-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja7101423
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An unprecedented intrinsic yellow phosphor with high PL quantum efficiency and a unique MOF-like organic-inorganic hybrid open framework has been synthesized under mild thermal conditions; the structure of NTHU-6 is built from small organic oxalate linkers and large inorganic hexameric octahedral Ga-O clusters; its extraordinary yellow emission was suspected to correlate with defects evoked by disorderliness near large pores with the template presumed to act as a sensitizer.
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