4.8 Article

Preparation of azafullerene derivatives from fullerene-mixed peroxides and single crystal X-ray structures of azafulleroid and azafullerene

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 38, Pages 12614-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja805072h

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Funding

  1. NNSFC [20632010, 20521202, 20472003]
  2. Ministry of Education of China
  3. Major State Basic Research Development Program [2006CB806201]

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Azafullerene was prepared by addition of hydroxylamine to a cage-opened fullerendione derivative and subsequent PCl5 induced rearrangement processes. X-ray structures were obtained for the azafullerene and its azafulleroid precursor.

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