Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 45, Pages 14910-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja804448p
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Funding
- NSF [NSF-CCF-05204490]
- MARCO Center for Advanced Materials and Devices
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A two-step chlorination/azidation process was reported to prepare azide-modified silicon(111) surfaces. XPS and IR analyses show the covalent bonding of azide with silicon. In combination with scanning tunneling microscopy and spectroscopy analyses, different kinetic rates, azide coverages, and surface-area distributions were derived depending on the azidation solvent.
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