Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 50, Pages 16828-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja804014y
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Funding
- U.S. DOE [DE-FG02-ER15244, DE-AC02-06CH 11357]
- AAUW fellow
- Argonne Laboratory-Grad Fellow
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Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by sotution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.
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