Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 50, Pages 16943-16946Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8039794
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Funding
- National Research Foundation of Korea [R01-2007-000-10899-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Diversely shaped porous coordination polymer particles (CPPs) were synthesized by a simple solvothermal reaction of 1,4-benzenedicarboxylic acid (H2BDC) and In(NO3)(3)center dot xH(2)O in DMF. The growth of crystalline CPPs was controlled through a particle growth blocking event involving blocking agent interaction with particular facets of CPPs and simultaneous particle growth interruption in a specific direction. Systematic reactions in the presence of various amounts of pyridine as a blocking agent were conducted to see the controlled CPP formation. Long rod, short rod, lump, and disk-shaped CPPs with hexagonal faces resulted in the presence of none, 1 equiv, 2 equiv, and 25 equiv of pyridine, respectively. The ultimate particle shape produced depends upon the amount of blocking agents used.
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