Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 1, Pages 26-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0776780
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The dinuclear Run(II)-Pd-II complex shows efficient H-2 production in the presence of triethylamine as a sacrificial electron and proton donor under visible light irradiation. XPS and TEM analyses reveal that photoreduction of Pd-II to Pd-0 causes dissociation of Pd from the complex to form colloids that are suggested to be the actual catalyst for H-2 production.
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