Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 29, Pages 9228-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja803370x
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Funding
- NIGMS NIH HHS [R37 GM043214, GM-43214, R37 GM043214-18, R37 GM043214-17, R01 GM043214] Funding Source: Medline
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N,N'-Diphenylguanidinium ion associated with the noncoordinating BArF counterion is shown to be an effective catalyst for the [3,3]-sigmatropic rearrangement of a variety of substituted allyl vinyl ethers. Highly enantioselective catalytic Claisen rearrangements of ester-substituted allyl vinyl ethers are then documented using a new C(2)-symmetric guanidinium ion derivative.
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