Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 2, Pages 452-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja710564b
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A catalytic amount of flouride salt is all that is required to generate high molecular weight poly(phenylene ethynylene)s from silylacetylene-fuctionalized monomers and C6F5. The sole side product is gaseous fluorotrimethylsilane and the catalyst is removed simply by washing with water. The polymerization proceeds through a reactive intermediate, causing significant deviation from theory describing the relationship between comonomer stoichiometry and degree of polymerization for classical step-growth polymerizations.
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