Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 43, Pages 14058-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja807129e
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Funding
- The Scripps Research Institute
- U.S. National Science Foundation [NSF CHE-0615716]
- Amgen 60 Inc.
- A. P. Sloan Foundation for a Fellowship
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Pd(II)-catalyzed intramolecular amination of Sp(2) and Sp(3) C-H bonds are developed using a combination of CuCl2 and AgOAc as the oxidant. The reaction protocol tolerates the presence of a double bond in the substrates. This catalytic reaction provides practical access to a wide range of beta-, gamma-, and delta-lactams.
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