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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 31, Pages 10082-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja804150k
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Calculations suggest that complexes of borane with N-heterocyclic carbenes (NHC) have B-H bond dissocation energies more then 20 Kcal/mol less than free borane, diborane, borane-THF, and related complexes. Values are in the range of popular radical hydrogen atom donors like tin hydrides (70-80 Kcal/mol). The resulting prediction that NHC borane complexes could be used as radical hydrogen atom donors was verified by radical deoxygenations of xanthates by using either AIBN or triethylborane as initiator.
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