Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 31, Pages 10086-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8042382
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A heterobimetallic complex with the first unspported bond between an actinide and a group 13 elements, (CpSiMe3)(3)U-AlCp star (Cp-star=C5Me5) (1), was synthesized by reaction of (CpSiMe3)(3)U and 1/4((CpAl)-Al-star)(4) in toluene. Density functional theory calculations indicate that the U-Al bond exhibits some covalent character resulting from a (CpAl)-Al-star -> U charge-transfer.
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