Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 43, Pages 14088-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja806311e
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Funding
- Kurata Memorial Hitachi Science and Technology Foundation
- Nagoya University
- MEXT, Japan
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The cooperative asymmetric catalysis of chiral tetraaminophosphonium carboxylate (P,S)-1-OCOR has been established, and its synthetic utility has been successfully demonstrated by application to the highly enantioselective direct Mannich-type reaction of azlactones with N-sulfonyl imines. The present study stimulates the cultivation of the potential of the chiral quaternary onium salt catalysis by the structural modification of organic anion.
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