4.8 Article

An extraordinary cylinder-to-cylinder transition in the aqueous assemblies of fluorescently labeled rod-coil amphiphiles

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 42, Pages 13858-13859

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja806128e

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Funding

  1. Korea Science and Engineering Foundation [R01-2006-000-11221-0]
  2. National Research Foundation of Korea [R01-2006-000-11221-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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We report an unprecedented cylinder-to-cylinder transformation in the self-assemblies of pyrene-labeled rod-coil molecules in water. The extraordinary morphological transformation can be monitored by a fluorescence variation from exciplex to excimer emissions, suggesting the rod-packing transition from antiparallel to interdigitated arrangements as a function of PEO coil length.

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