4.8 Article

Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 44, Pages 14450-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja807188s

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When combined with a chiral phosphate counteranion, a chiral diamine-ligated Ir(III) catalyst displayed excellent enantioselectivities in the asymmetric hydrogenation of a wide range of acyclic imines, affording chiral amines in up to 99% ee.

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