4.8 Article

Fragmentation of an Infinite ZnO2 Square Plane into Discrete [ZnO2]2- Linear Units in the Oxyselenide Ba2ZnO2Ag2Se2

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 44, Pages 14426-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja8063414

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Funding

  1. EPSRC [EP/E025447/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/E025447/1] Funding Source: researchfish

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Analysis of single crystal X-ray diffraction, neutron powder diffraction, electron diffraction and Zn-K-edge EXAFS data show that Ba2ZnO2Ag2Se2 contains unusual isolated [ZnO2](2-) moieties resulting from fragmentation of a ZnO2 infinite plane placed under tension.

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