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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 16, Pages 5388-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja710227g
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The adsorption of octylamine on Au(111) under ultrahigh vacuum conditions is investigated. The molecules surprisingly undergo a thermally activated chemical reaction, resulting in formation of trioctylamine as confirmed both by X-ray photoelectron spectroscopy (XPS) and by comparison to the scanning tunneling microscopy (STM) signature of trioctylamine deposited directly onto the surface.
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