4.8 Article

Chain-terminus triggered chiral memory in an optically inactive 310-helical peptide

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 37, Pages 12266-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja805647k

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A new optically inactive 3(10)-helical peptide with a side-chain cross-linking was found to exhibit chiral memory stored in the peptide backbone, whose chirality was induced by a noncovalent interaction of a chiral molecule at the N-terminal end of the peptide.

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