Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 36, Pages 12128-12138Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja803535s
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- National Science Foundation [CHE-039878]
- National Institutes of Health [GM 23851]
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The nature of H(H2O)(n)(+) cations for n = 3-8 with weakly basic carborane counterions has been studied by IR spectroscopy in benzene and dichloroethane solution. Contrary to general expectation, neither Eigen-type H3O center dot 3H(2)O(+) nor Zundel-type H5O2+center dot 4H(2)O ions are present. Rather, the core species is the H7O3+ ion.
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