Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 18, Pages 5850-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja800575v
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The surface ab planes of the M1 phase exposed selectively after atomic layer deposition (ALD) of alumina followed by crushing showed significantly improved selectivity to acrylonitrile during propane ammoxiclation. The results demonstrated the importance of surface ab planes for the activity and selectivity of the M1 phase in propane ammoxiclation and general utility of surface modification by ALD in studies of catalytic behavior of surface planes in layered mixed metal oxides.
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