Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 44, Pages 14378-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8045475
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Funding
- NSF [CHE 05-50232]
- Zymes, LLC
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Treatment of beta,beta-disubstituted-alpha,beta-unsaturated ketones bearing a ketone residue with in situ generated, catalytic CuH ligated by a nonracemic ligand leads to three newly created adjacent chiral centers. Excellent de's and ee's are obtained for several examples studied.
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