Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 33, Pages 10834-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja801508q
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Funding
- Royal Society
- EPSRC
- GlaxoSmithKline
- Engineering and Physical Sciences Research Council [GR/S76908/01] Funding Source: researchfish
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A simple water-soluble naphthalenedithiol building block is converted quantitatively into a series of octameric [2]-catenanes, composed of two interlocked molecular squares. When this mixture is re-equilibrated in the presence of an adamantyl ammonium guest, the catenanes disassemble into their macrocyclic components that bind the guest with nanomolar affinity in water.
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