Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 46, Pages 15246-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja806122r
Keywords
-
Categories
Funding
- American Chemical Society Petroleum Research Fund [42943-131]
- Texas Advanced Research Program [0036440013-2006]
- HHMI
Ask authors/readers for more resources
A bis-phenanthroline [2]catenane copper complex, consisting of one olefinic macrocycle and one nonolefinic macrocycle, underwent an entropy-driven ring-opening olefin metathesis polymerization (ROMP) to provide a polypseudorotaxane. The polymerization featured an average degree of polymerization of ca. 63 wherein the polymer was effectively saturated with threaded macrocycles. Removal of the copper led to near complete release of the macrocycles from the polymer backbone.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available