Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 4, Pages 1128-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja077862l
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Funding
- NIGMS NIH HHS [R01GM077635, R01 GM077635-01A1, R01 GM077635] Funding Source: Medline
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An efficient, copper-catalyzed method for the arylation, alkenylation, and benzylation of polyfluoroarenes has been developed. Arenes containing two or more fluorine substituents on the aromatic ring can be efficiently functionalized. The best results are obtained by using a combination of copper iodide catalyst, phenanthroline ligand, aryl bromide or aryl iodide coupling partner, and DMF or DMF/xylene mixed solvent.
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