Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 34, Pages 11248-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja803344v
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- National Institutes of Health
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Rhodium-catalyzed C-H insertion of hydroxylamine-derived sufamate esters makes possible the synthesis of unique oxathiadiazinane heterocycles, which upon mild reduction furnish differentially substituted 1,2-diamine products. This highly chemo- and diastereoselective transformation underscores the power of catalytic C-H functionalization as a general approach to C-N bond construction.
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