Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 40, Pages 13222-13224Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8047078
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Funding
- National Institutes of Health [CA28824]
- National Center for Research Resources [RR-03037]
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Microwave induces two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate mixed anhydride (FCMA) is proposed as the reactive intermediate, which undergoes 1,3-O-->N acyl transfer to give the observed product. The formation and survival of the labile FCMA system has been evaluated.
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