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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 21, Pages 6734-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8018675
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The first highly conductive polyselenophene, namely, poly(3,4-ethylenedioxyselenophene) (PEDOS), was synthesized by taking advantage of a novel method for efficiently contracting the selenophene ring. PEDOS shows a relatively low band gap (1.4 eV), very high stability in the oxidized state, and a well-defined spectroelectrochemistry.
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